PR-040
Material High cis Butadiene Rubber
Cis-Content >95%
TensileStrength 20-30 MPa
ElongationAtBreak >500%
GlassTransitionTemperature -90°C to -100°C
SpecificGravity 0.92
HardnessShoreA 50-70
AbrasionResistance High
ThermalStability Moderate
Polymerization Solution Polymerization
ResistanceTo Excellent flexibility and weather resistance
FAQ
What is High cis Butadiene Rubber and what are its primary applications?

High cis Butadiene Rubber is a type of synthetic rubber that is produced through the polymerization of butadiene. The term "high cis" refers to the configuration of the polymer chain where the double bonds are in the "cis" position, which imparts unique mechanical properties to the rubber. This specific configuration is achieved by using catalysts during the polymerization process, predominantly rare earth-based or nickel-based catalysts, to ensure that the double bonds maintain the desired orientation. High cis Butadiene Rubber is renowned for its resilience, abrasion resistance, and notable elasticity. These properties make it a preferred choice in various applications, particularly where flexibility and the ability to withstand repeated deformations are crucial.

The primary applications of High cis Butadiene Rubber include the manufacturing of tires, where it contributes to improved rolling resistance, reduced wear, and enhanced fuel efficiency. Its low glass transition temperature provides excellent cold resistance, making it suitable for use in areas with extreme climates. Additionally, it is used in the production of golf balls, plastic modifiers, and industrial goods such as conveyor belts and hoses. The resilience and durabilities of this rubber meet the high-performance standards necessary in these products. Moreover, it finds applications in the footwear industry, especially in shoe soles, due to its excellent cushioning properties and wear resistance. High cis Butadiene Rubber is also valued in the medical sector, used in making seals and gaskets because of its inert properties and resistance to a wide range of chemicals. These various applications underline its versatility and significance across different industries, driven by its physical and chemical attributes.

How does the structure of High cis Butadiene Rubber affect its properties?

The unique structure of High cis Butadiene Rubber significantly influences its properties, primarily due to the polymer chain configuration, which is predominantly composed of cis-1,4 butadiene units. In this configuration, the butadiene monomers are aligned in such a way that the double bonds in the polymer backbone are in the cis position. This specific arrangement is critical as it imparts certain mechanical properties such as enhanced flexibility and resilience. The high degree of cis-configuration, often exceeding 95%, leads to a lower glass transition temperature, making the rubber highly elastic over a broad temperature range, from very low to moderately high temperatures. This elasticity is essential for applications where repeated stretching and recovery are required, such as in tires and various industrial products.

The structural trait of having a high cis content results in a fine balance between toughness and flexibility. This structural integrity enables the rubber to resist wear, thus prolonging the lifespan of products in which it is used, like tires. Additionally, the amorphous, kinked nature of the cis-configured molecules means that the rubber exhibits lower crystallinity, enhancing its flexibility. Furthermore, this structure affords High cis Butadiene Rubber low hysteresis loss, translating to reduced energy loss during deformation. This characteristic is particularly beneficial in tire applications, contributing to better fuel efficiency as it reduces rolling resistance.

Another significant impact of its structure is its chemical resistance, especially to oils and other hydrocarbons. The strong C=C double bonds along the polymer chain confer stability against oxidative degradation. However, it is worth noting that while the high cis structure contributes positively to its mechanical and physical properties, it also means that this rubber is susceptible to ozone and UV degradation, factors that might necessitate the addition of protective additives or coatings in certain applications. Overall, the structure-property relationship in High cis Butadiene Rubber is a classic example of how molecular architecture can dictate material performance, making it suitable for diverse, demanding applications.

What advantages does High cis Butadiene Rubber offer over other types of synthetic rubbers?

High cis Butadiene Rubber offers several advantages over other types of synthetic rubbers, primarily due to its distinct structural properties and resultant mechanical performance. One key advantage is its superior abrasion resistance, which makes it highly suitable for applications requiring long-lasting materials, such as tires and conveyor belts. Compared to other synthetic rubbers like styrene-butadiene rubber (SBR) or nitrile rubber, the high cis content grants this material excellent resilience and the ability to undergo substantial deformations without experiencing permanent set. This property is particularly advantageous in scenarios that require materials to sustain repeated flexing and bending, maintaining their original shape over extended periods.

The low glass transition temperature of High cis Butadiene Rubber also provides significant benefits. This characteristic ensures that the rubber remains flexible even at sub-zero temperatures, making it suitable for applications in colder climates where other rubbers might become brittle and fail. This flexibility is critical in automotive applications, where tires are expected to perform under various temperature conditions.

Another advantage is its superior dynamic properties, manifesting in lower hysteresis losses. This means that products made from High cis Butadiene Rubber exhibit less energy dissipation as heat under cyclic stress, which is essential for high-performance tires designed to achieve better fuel economy through reduced rolling resistance. In comparison to other elastomers like SBR, this efficiency in energy transfer is a distinct advantage.

Additionally, High cis Butadiene Rubber displays excellent chemical stability, especially against hydrocarbon oils and other non-polar substances. This chemical resilience is beneficial in scenarios involving exposure to various industrial fluids. However, it does need some protective measures against degradation from ozone and UV light, similar to natural rubber, which is a small downside compared to its numerous advantages.

Finally, its compatibility with other rubbers and compound formulations provides a versatile platform for engineers and designers to tailor materials for specific applications. The ability to blend with other elastomers allows for the customization of properties such as hardness, color, and overall durability, expanding its utility across sectors from automotive and industrial to consumer goods. These advantages, taken together, underscore why High cis Butadiene Rubber remains a material of choice in demanding environments where durability, flexibility, and efficiency are of paramount concern.

Are there any environmental considerations associated with the production and use of High cis Butadiene Rubber?

The production and use of High cis Butadiene Rubber, like many synthetic materials, present several environmental considerations that are essential to acknowledge, particularly in light of increasing sustainability demands. The primary raw material for producing High cis Butadiene Rubber is butadiene, a byproduct of the petrochemical industry. As with many petroleum-derived materials, the extraction and processing of raw materials involve energy-intensive processes with associated carbon emissions. This dependency on non-renewable resources highlights a key environmental challenge; however, efforts are ongoing within the industry to mitigate such impacts through improved efficiency and alternative raw material sources.

During production, the polymerization process used to create High cis Butadiene Rubber involves catalysts, which can lead to byproduct formation and waste management challenges. Handling and disposal protocols must be carefully managed to minimize environmental impacts. Advances in catalysis have aimed to reduce waste and improve process efficiency, lowering the environmental footprint. Additionally, ongoing research into biobased sources for butadiene, such as bio-butadiene from biomass or renewable feedstocks, offers potential pathways for reducing reliance on fossil fuels and the corresponding environmental impact.

The environmental implications extend to the use phase of High cis Butadiene Rubber, particularly in the disposal of rubber products at the end of their life cycle. Many products, notably tires, can be difficult to recycle and often end up in landfills where they pose environmental hazards due to their non-biodegradability. There is a significant focus within the industry on enhancing recycling technologies, such as pyrolysis and devulcanization, to recover valuable materials from used rubber and reduce waste.

Sustainability efforts are addressing these considerations by implementing circular economy principles, promoting product design for recyclability, and enhancing collection systems for used rubber products. Additionally, there are emerging practices in product stewardship, which encourage manufacturers to take responsibility for the entire lifecycle of their products, thus driving innovation in material recovery and reuse.

Overall, while the production and use of High cis Butadiene Rubber do pose environmental challenges, the industry is actively pursuing strategies to address these issues. Continuous improvements in production efficiency, material sourcing, and end-of-life management are vital to minimizing environmental impacts, aligning with global sustainability goals. Crucially, ongoing research and development in green chemistry and materials science are poised to further transform the lifecycle management of synthetic rubbers and their environmental footprint in the years to come.

How does High cis Butadiene Rubber contribute to the performance of automotive tires?

High cis Butadiene Rubber is integral to the performance of automotive tires due to its unique mechanical properties, which enhance several key aspects of tire functionality. Firstly, its high abrasion resistance is crucial, as it ensures longevity in tire treads exposed to constant friction and varying road conditions. This translates to a longer lifespan for the tires, reducing replacement frequency and, consequently, the environmental impact associated with tire manufacturing and disposal.

The low glass transition temperature of High cis Butadiene Rubber means that tires can retain elasticity and maintain grip across a broad temperature range. This feature is vital for all-season tires, ensuring they remain pliable and capable of providing adequate traction whether on icy roads or during the heat of summer. The ability to perform consistently across different climates helps enhance safety and vehicle control for drivers.

Another noteworthy contribution of High cis Butadiene Rubber to tire performance is its impact on fuel efficiency. The material's low hysteresis loss reduces the rolling resistance of tires, which in turn lowers the energy needed to keep a vehicle in motion. This attribute is particularly beneficial in reducing fuel consumption, offering economic advantages for the user while simultaneously contributing to lower emissions and environmental benefits.

High cis Butadiene Rubber also improves the ride comfort by absorbing and dissipating road shocks before they escalate to the vehicle's cabin. This absorption is due to its excellent damping properties, which cushion the impact and provide smoother rides. Furthermore, the polymer's ability to blend with other materials allows manufacturers to fine-tune tire formulas to meet specific performance needs, such as optimizing the balance between wet and dry traction or enhancing cornering stability.

Additionally, the adherence of High cis Butadiene Rubber compounds to road surfaces contributes significantly to gripping performance, ensuring excellent response under various driving conditions. This property is especially critical for sporty and high-performance vehicles where handling precision is prioritized. The material's resilience supports enhanced steering responsiveness, especially during rapid directional changes, thus further affirming its suitability in performance-oriented automotive tire applications.

Overall, the incorporation of High cis Butadiene Rubber in tire manufacturing results in products that offer improved durability, safety, fuel efficiency, and comfort. These factors seamlessly intertwine to elevate the standard of automotive performance, responding adeptly to the growing consumer demand for high-quality, longer-lasting, and environmentally friendly tires. With ongoing advancements in material science, High cis Butadiene Rubber continues to play a pivotal role in the evolution of automotive tire technology.
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